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EP0073614A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Double-tuned single coil probe for nuclear magnetic resonance spectrometer

Assignee: Monsanto Co
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Filing: 1982-08-20
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Granted: —
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Expires: 2002-08-20
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Abstract

Abstract A double-tuned single coil probe for a nuclear magnetic resonance spectrometer having improved sensitivity is described comprising a double-tuned circuit means in which the low frequency irradiation is fed to a transmission line through an inductor means. The double-tuned circuit means of the invention may be remotely disposed from the magnetic field which results in greater sensitivity.

Inventors

  • 👤 Robert Allen Mckay

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 09:30
CPC Classifications
G; G01; G01R; G01R33/00; G01R33/20; G01R33/28; G01R33/32; G01R33/36; G01R33/3628; G01R33/3635; G01R33/62

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 134 words
A double-tuned single coil probe for a nuclear magnetic resonance (NMR) spectrometer which probe comprises a sample coil connected to a double-tuned circuit means comprising a high frequency irradiation means and a low frequency irradiation means in which the two frequencies have a ratio of about at least three to one or more and are in the radio frequency (RF) range, in which the high frequency irradiation means is connected to the sample coil through a transmission line means comprising a transmission line of a length of about one half of the high frequency wavelength, and the low frequency irradiation means is connected to the sample coil through the aforesaid transmission line means through an inductor means connected to the transmission line at about the point of minimum impedance for the high frequency radiation.
Claim 2
Dependent Claim 134 words
A double-tuned single coil probe for a nuclear magnetic resonance (NMR) spectrometer which probe comprises a sample coil connected to a double-tuned circuit means comprising a high frequency irradiation means and a low frequency irradiation means in which the two frequencies have a ratio of about at least three to one or more and are in the radio frequency (RF) range, in which the high frequency irradiation means is connected to the sample coil through a transmission line means comprising a transmission line of a length of about one half of the high frequency wavelength, and the low frequency irradiation means is connected to the sample coil through the aforesaid transmission line means through an inductor means connected to the transmission line at about the point of minimum impedance for the high frequency radiation.
Claim 3
Dependent Claim 52 words
The probe of Claim 1 comprising a probe which sufficiently radiates a sample with both high and low frequency radiation to excite the NMR of the sample nuclei at both frequencies and transmits the signals generated by the sample NMR to a high frequency detection means and a low frequency detection means.
Claim 4
Dependent Claim 31 words
The probe of Claim 2 comprising an inductor means which provides an inductive impedance to match the impedance of the low frequency means to the impedance of the transmission line means.
Claim 5
Dependent Claim 28 words
The probe of Claim 3 in which the low frequency irradiation means comprises an RF generator connected to the inductor means through a capacitive tuning and matching circuit.
Claim 6
Dependent Claim 28 words
The probe of Claim 4 in which the high frequency irradiation means comprises an RF generator connected to the transmission line through a capacitive tuning and matching circuit.
Claim 7
Dependent Claim 15 words
The probe of Claim 5 in which the transmission line-is a coaxial cable transmission line.
Claim 8
Dependent Claim 36 words
The probe of Claim 6 in which the double-tuned circuit means is remotely disposed from the sample cail so that when in use with an NMR spectrometer it can be positioned outside the magnetic field thereof.
Claim 9
Dependent Claim 14 words
The probe of Claim 7 in which the inductor means is an inductor coil.

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