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EP0053471A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Curable silicone compositions comprising liquid resin and uses thereof

Assignee: Dow Silicones Corp
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Filing: 1981-11-25
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Granted: —
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Expires: 2001-11-25
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Abstract

Abstract Curable silicone compositions are disclosed which comprise a liquid copolymeric organopolysiloxane comprising Si0<sub>2</sub> and silicon-bonded hydroxyl radicals and/or silicon-bonded hydrogen radicals in varying amounts and a polydiorganosiloxane containing silicon-bonded vinyl radicals and/or silicon-bonded hydroxyl radicals. The curable silicone compositions are useful as coatings for substrates.

Inventors

  • 👤 John Donald Blizzard

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-06 07:57
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/42; C08G77/44; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08L; C08L83/00; C08L83/04; C08G77/20; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31609; Y10T428/31612; Y10T428/31652; Y10T428/31663; Y10T428/31725; Y10T428/31739

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 211 words
A composition comprising (I) a liquid copolymeric organopolysiloxane, prepared by a method comprising (A) forming a homogeneous mixture having an acid number greater than zero and characterized by (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R 3 SiO l/2 siloxane units and SiO 4/2 siloxane units wherein the ratio of the number of said R 3 SiO l/2 siloxane units to the number of said Si0 4/2 siloxane units has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen radical per molecule of said organohydrogenpolysiloxane, and (B) heating said homogeneous mixture to remove substantially all of said organic solvent therefrom and (II) a polydiorganosiloxane having the formula ZR''' 2 SiO(R''' 2 SiO) c SiR''' 2 Z wherein Z denotes hydroxyl or R''' and each R''' denotes independently, a monovalent hydrocarbon radical, there being an average of at least two vinyl radicals or silicon-bonded hydroxyl radicals per molecule and c has a value sufficient to provide a viscosity of from 0.1 to 10,000 Pa·s at 25°C for the polydiorganosiloxane.
Claim 2
Dependent Claim 211 words
A composition comprising (I) a liquid copolymeric organopolysiloxane, prepared by a method comprising (A) forming a homogeneous mixture having an acid number greater than zero and characterized by (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R 3 SiO l/2 siloxane units and SiO 4/2 siloxane units wherein the ratio of the number of said R 3 SiO l/2 siloxane units to the number of said Si0 4/2 siloxane units has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen radical per molecule of said organohydrogenpolysiloxane, and (B) heating said homogeneous mixture to remove substantially all of said organic solvent therefrom and (II) a polydiorganosiloxane having the formula ZR''' 2 SiO(R''' 2 SiO) c SiR''' 2 Z wherein Z denotes hydroxyl or R''' and each R''' denotes independently, a monovalent hydrocarbon radical, there being an average of at least two vinyl radicals or silicon-bonded hydroxyl radicals per molecule and c has a value sufficient to provide a viscosity of from 0.1 to 10,000 Pa·s at 25°C for the polydiorganosiloxane.
Claim 3
Dependent Claim 31 words
A composition according to claim 1 wherein the liquid copolymeric organopolysiloxane is prepared from a homogeneous mixture having an acid number of from 0.1 to 1, extrapolated to the solvent-free state.
Claim 4
Dependent Claim 39 words
A composition according to claim 2 wnerein the ratio of the total number of silicon-bonded hydrogen atoms in component (b) to the total number of silicon-bonded hydroxyl radicals in component (a) has a value of at least about 2.
Claim 5
Dependent Claim 56 words
A composition according to claim 3 wherein the liquid copolymeric organopolysiloxane is prepared from a resinous copolymeric siloxane consisting of (CH 3 ) 3 SiO l/2 siloxane units and Si0 4/2 siloxane units and having a silicon-bonded hydroxyl content of from 1 to 5 percent by weight and an acid number of from 0.3 to 1.4.
Claim 6
Dependent Claim 65 words
A composition according to claim 4 wnerein the liquid copolymeric organopolysiloxane is prepared from an organonydrogenpolysiloxane having the formula (R")(CH 3 ) 2 SiO[(CH 3 ) 2 SiO] a [(CH 3 )(H)SiO] b -Si(CH 3 ) 2 (R") wherein each R" denotes, independently, a methyl radical or a hydrogen radical and a and b denote numbers, each having an average value of zero or more.
Claim 7
Dependent Claim 44 words
A composition according to claim 5 wherein the organohydrogenpolysiloxane that is used to prepare the liquid copolymeric organopolysiloxane has the formula (CH 3 ) 3 SiO[(CH 3 )(H)SiO] b Si(CH 3 ) 3 wherein b has an average value of from 30 to 7U.
Claim 8
Dependent Claim 35 words
A composition according to claim 6 wherein the liquid copolymeric organopolysiloxane is prepared from 40 to 60 parts by weight of resinous copolymeric siloxane and from 4 0 to 60 parts by weight of organohydrogenpolysiloxane.
Claim 9
Dependent Claim 62 words
A composition according to claim 7 wherein the polydiorganosiloxane has the formula (CH 2 =CH)(CH 3 )Si[(CH 3 ) 2 Si0] c(1-d) [(CH 3 )(CH 2 =CH)SiO] cd -Si(CH 3 ) 2 (CH=CH 2 ) wherein d has a value sufficient to limit the total number of vinyl radicals to no more than 5 percent of all organic radicals in the polydiorganosiloxane.
Claim 10
Dependent Claim 12 words
A composition according to claim 1, further comprising an organohydrogenpolysiloxane curing agent.
Claim 11
Dependent Claim 18 words
A composition obtained by mixing a curing amount of a curing catalyst with the composition of claim 9.
Claim 12
Dependent Claim 9 words
A substrate bearing the cured composition of claim 10.

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