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EP0049686A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Hydroquinone derivatives, their preparation and use in photographic materials

Assignee: Novartis AG
•
Filing: 1981-09-28
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Granted: —
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Expires: 2001-09-28
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Abstract

Abstract Substituted hydroquinone compounds of the formula wherein R 1 to R 4 are hydrogen or alkyl and Z is an aromatic ring or a group of the formula -X-Y-X-, wherein X is an aromatic ring and Y is an electron withdrawing group, are incorporated as developers into photographic materials. These materials are suitable for activation processings.

Inventors

  • 👤 Stephen Roderick Postle
  • 👤 Patrick David Pryce Thomas
  • 👤 Brian Ronald David Whitear

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 01:12
CPC Classifications
C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/60; C07D213/78; C07D213/79; C07C; C07C317/00; C07D307/00; C07D307/02; C07D307/34; C07D307/56; C07D307/68; G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/42; G03C5/00; G03C5/26; G03C5/29; G03C5/30; G03C5/3021; Y; Y10; Y10S; Y10S430/00; Y10S430/156

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 48 words
A substituted hydroquinone compound of formula wherein R 1 to R 4 are each hydrogen or alkyl having from 1 to 4 carbon atoms, Z is an aromatic ring or is a group -X-Y-X- wherein X is an aromatic ring and Y is an electron withdrawing linking group.
Claim 2
Dependent Claim 48 words
A substituted hydroquinone compound of formula wherein R 1 to R 4 are each hydrogen or alkyl having from 1 to 4 carbon atoms, Z is an aromatic ring or is a group -X-Y-X- wherein X is an aromatic ring and Y is an electron withdrawing linking group.
Claim 3
Dependent Claim 18 words
A compound according to claim 1, wherein R 1 to R 4 are each hydrogen, methyl or t-butyl.
Claim 4
Dependent Claim 16 words
A compound according to claim 2 wherein each of R 1 to R 4 are hydrogen.
Claim 5
Dependent Claim 21 words
A compound according to any one of claims 1 to 3 wherein Z is a monocyclic 5- or 6-membered aromatic ring.
Claim 6
Dependent Claim 10 words
A compound according to claim 4 wherein Z is phenylene.
Claim 7
Dependent Claim 61 words
A compound according to any one of claims 1 to 5 wherein Y is -SO 2 -, -SO-, -CO- or a group of the formula =PO-A, wherein A is alkyl or alkoxy each having 1 to 4 carbon atoms, phenyl, phenoxy or a group of the formula wherein R 1 to R 4 and X are as defined in claim 1.
Claim 8
Dependent Claim 20 words
A compound according to any one of claims 1 to 6, wherein X is a monocyclic aromatic 6-membered ring system.
Claim 9
Dependent Claim 10 words
A compound according to claim 7, wherein X is phenylene.
Claim 10
Dependent Claim 42 words
A compound according to any one of claims 1 to 8, wherein R 1 to R 4 are hydrogen and Z is phenylene, furylene, pyridinylene or a group of the formula -X-Y-X-, wherein X is phenylene and Y is -SO 2 -.
Claim 11
Dependent Claim 63 words
A process for the manufacture of a substituted hydroquinone compound according to claim 1, wherein 1 mole of the acid chloride of formula wherein Z is as defined in claim 1, is reacted with 2 moles of the hydroquinone of formula wherein R 1 to R 4 are as defined in claim 1, in the presence of an organic solvent and a base.
Claim 12
Dependent Claim 47 words
A process for the manufacture of a substituted hydroquinone compound according to claim 1, wherein 2 moles of the hydroquinone compound of formula (3) dissolved in an aqueous sodium carbonate solution is reacted with 1 mole of the acid chloride of formula (2) in an aqueous medium.
Claim 13
Dependent Claim 35 words
. 12. Photographic silver halide material which comprises on a support at least one colloid silver halide layer and at least one colloid layer which comprises at least one substituted hydroquinone compound of formula (1).
Claim 14
Dependent Claim 35 words
. 12. Photographic silver halide material which comprises on a support at least one colloid silver halide layer and at least one colloid layer which comprises at least one substituted hydroquinone compound of formula (1).
Claim 15
Dependent Claim 29 words
Photographic material according to claim 12 which comprises 0.1 to 1.0 mole of the compound of formula (1) per 1.5 moles of silver halide present in the photographic material.
Claim 16
Dependent Claim 33 words
A process for the production of the photographic silver halide material according to claim 12, wherein at least one substituted hydroquinone compound of formula (1) is incorporated into at least one colloid layer.

References Cited (Backward Citations)

DE2112483A1 Cited
US3962314A Cited

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