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EP0035917A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

A photosensitive composition, an article comprising the composition and the use of the composition as a photoresist

Assignee: Eastman Kodak Co
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Filing: 1981-03-11
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Granted: —
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Expires: 2001-03-11
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Abstract

Abstract The properties of a dichromated hydrophilic colloid photosensitive composition are improved by the incorporation of certain copolymer latices. More particularly, the copolymer particles in the latex have from 75 to 95 percent by weight of at least one repeating unit conforming to the structure: and from 5 to 25 percent by weight of at least one repeating unit conforming tothe structure: wherein: R 1 is hydrogen or methyl; R 2 is phenyl, substituted phenyl or a straight- or branched-chain alkoxycarbonyl group having 2 to 8 carbon atoms; R 3 is hydrogen or methyl; R' is -NR 5 R 6 or -OR' wherein R 5 and R 6 are independently selected from hydrogen, alkyl or substituted alkyl having 1 to 8 carbon atoms and alkyl containing one or more hetero atoms in the alkyl chain, and R' is hydroxyalkyl having 1 to 8 carbon atoms. The photosensitive composition may be used as a photoresist in preparing filter arrays for solid state color imaging devices.

Inventors

  • 👤 Richard Calvin Sutton
  • 👤 Thomas William Martin

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 13:48
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/04; G03F7/0005; G03F7/0007; Y; Y10; Y10S; Y10S430/00; Y10S430/163

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 152 words
.A photosensitive composition comprising: (a) water, (b) a hydrophilic colloid and (c) a dichromate photocrosslinking agent, characterized in that the photosensitive composition further comprises a copolymer latex containing copolymer particles having from 75 to 95 percent by weight of at least one repeating unit conforming to the structure: and from 5 to 25 percent by weight of at least one repeating unit conforming to the structure: wherein: R 1 is hydrogen or methyl; R 2 is phenyl, substituted phenyl or a straight- or branched-chain alkoxycarbonyl group having 2 to 8 carbon atoms; R 3 is hydrogen or methyl; R 4 is -NR 5 R 6 or -OR 7 wherein R S and R 6 are independently selected from hydrogen, alkyl or substituted alkyl having 1 to 8 carbon atoms and alkyl containing one or more hetero atoms in the alkyl chain, and R 7 is hydroxyalkyl having 1 to 8 carbon atams.
Claim 2
Dependent Claim 152 words
.A photosensitive composition comprising: (a) water, (b) a hydrophilic colloid and (c) a dichromate photocrosslinking agent, characterized in that the photosensitive composition further comprises a copolymer latex containing copolymer particles having from 75 to 95 percent by weight of at least one repeating unit conforming to the structure: and from 5 to 25 percent by weight of at least one repeating unit conforming to the structure: wherein: R 1 is hydrogen or methyl; R 2 is phenyl, substituted phenyl or a straight- or branched-chain alkoxycarbonyl group having 2 to 8 carbon atoms; R 3 is hydrogen or methyl; R 4 is -NR 5 R 6 or -OR 7 wherein R S and R 6 are independently selected from hydrogen, alkyl or substituted alkyl having 1 to 8 carbon atoms and alkyl containing one or more hetero atoms in the alkyl chain, and R 7 is hydroxyalkyl having 1 to 8 carbon atams.
Claim 3
Dependent Claim 28 words
The composition according to Claim 1 wherein R 1 and R 3 are each hydrogen, R 2 is phenyl and R 4 is -N R 5 R 6.
Claim 4
Dependent Claim 20 words
The composition according to Claim 2 wherein R 5 is hydrogen or methyl and R 6 is hydrogen or alkoxyalkyl.
Claim 5
Dependent Claim 14 words
The composition according to Claim 1 wherein said copolymer is poly(styrene-co-acrylamide) (weight ratio 90:10).
Claim 6
Dependent Claim 16 words
The composition according to Claim 1 wherein said copolymer is poly[styrene-co-N-(isobutoxymethyl)acrylamide] (weight ratio 80:20 or 90:10).
Claim 7
Dependent Claim 17 words
The composition according to any one of Claims 1 to 5 wherein said hydrophilic colloid is gelatin.
Claim 8
Dependent Claim 26 words
The composition according to any one of Claims 1 to 6 wherein the weight ratio of hydrophilic colloid to latex copolymer is between 15:1 to 7:1.
Claim 9
Dependent Claim 35 words
An article comprising a polyester layer having coated thereon a layer of a photosensitive composition, characterized in that the photosensitive composition is a composition according to Claim 1 from which the water has been removed.
Claim 10
Dependent Claim 13 words
The use of a photosensitive composition according to Claim 1 as a photoresist.
Claim 11
Dependent Claim 92 words
A process for producing a color filter array in a dye receiving layer on a solid-state imaging device, which process comprises: a) coating a photosensitive composition on the dye receiving layer, b) exposing and processing the photosensitive composition to produce window areas which correspond to a set of filter elements to be formed in the color filter array, c) heat-transferring dye into the dye receiving layer through the window areas, and d) removing the remainder of the photosensitive composition, characterized in that the photosensitive composition is a composition according to Claim 1.

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