EP0032375A1
Expired / Lapsed
EP
⏱️ 0.0 years remaining
Electrically conductive polyetherester elastomers
Assignee: EIDP Inc
•
Filing: 1981-01-07
•
Granted: —
•
Expires: 2001-01-07
Abstract
Abstract Conductive elastomeric compositions consisting essen. tially of a blend of a copolyetherester having 45-85 weight percent of long chains and 15-55 weight percent of short chains and melting at at least 90°C with a conductive filler consisting of carbon black or a mixture of carbon black with graphite, the resistivity of such compositions being less than about 2 ohm.cm can be fabricated or cast into thin, self-supporting films or sheets. Articles made from these compositions find utility in electrical and electronic equipment, business machines, and in applications where good aging properties are important.
Inventors
- 👤 Henry Joseph Stinger
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-06 05:24
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/24; C; C08; C08K; C08K3/00; C08K3/02; C08K3/04; C08L; C08L67/00; C08L67/02; C08L67/025; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2918; Y10T428/30
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
215 words
An electrically conductive composition consisting essentially of a uniform mixture of: (A) 100 parts of a copolyetherester having a melting point of at least about 90°C and containing 45-85 weight percent of long-chain ester units represented by the following formula (1) and 15-55 weight percent of short-chain ester units represented by the following formula (2) wherein R is a divalent radical remaining after removal of carboxyl groups from an aromatic or aliphatic dicarboxylic acid having a molecular weight of less than 300; G is a divalent radical remaining after the removal, of terminal hydroxyl groups from a poly(alkylene oxide) glycol HO-G-OH having a number average molecular weight of about 600-3500 and a carbon/oxygen atomic ratio of at least 2.5; and D is a divalent radical remaining after removal of hydroxyl groups from a diol HO-D-OH having a molecular weight of less than about 250; and (B) 60-110 parts of a conductive filler selected from the group consisting of carbon black and a mixture of carbon black and graphite, the proportion of carbon black in such a mixture being no less than about 20 weight percent; the resistivity of said electrically conductive composition being less than about 2 ohm.cm, its tensile strength at break at.least about 10 MPa, and its extension at break at least 20%.
Claim 2
Dependent Claim
215 words
An electrically conductive composition consisting essentially of a uniform mixture of: (A) 100 parts of a copolyetherester having a melting point of at least about 90°C and containing 45-85 weight percent of long-chain ester units represented by the following formula (1) and 15-55 weight percent of short-chain ester units represented by the following formula (2) wherein R is a divalent radical remaining after removal of carboxyl groups from an aromatic or aliphatic dicarboxylic acid having a molecular weight of less than 300; G is a divalent radical remaining after the removal, of terminal hydroxyl groups from a poly(alkylene oxide) glycol HO-G-OH having a number average molecular weight of about 600-3500 and a carbon/oxygen atomic ratio of at least 2.5; and D is a divalent radical remaining after removal of hydroxyl groups from a diol HO-D-OH having a molecular weight of less than about 250; and (B) 60-110 parts of a conductive filler selected from the group consisting of carbon black and a mixture of carbon black and graphite, the proportion of carbon black in such a mixture being no less than about 20 weight percent; the resistivity of said electrically conductive composition being less than about 2 ohm.cm, its tensile strength at break at.least about 10 MPa, and its extension at break at least 20%.
Claim 3
Dependent Claim
43 words
A composition of claim 1 wherein the polymeric glycol HO-G-OH is selected from the group consisting of poly(tetramethylene oxide) glycol, random copolymers of ethylene oxide and 1,2-propylene oxide, block copolymers of ethylene oxide and 1,2-propylene oxide, and copolymers of tetrahydrofuran with ethylene oxide.
Claim 4
Dependent Claim
11 words
A composition of claim 2 wherein the diol HO-D-OH is 1,4-butanediol.
Claim 5
Dependent Claim
16 words
A composition of claim 1 wherein R is selected from the group 1,2-phenylene, 1,3-phenylene, and 1,4-phenylene.
Claim 6
Dependent Claim
55 words
A composition of claim 1 wherein the conductive filler is a carbon black having a surface area of more than 30 m 2 /g, as determined by nitrogen absorption; a particle size of less than 70 pm, determined by electron microscopy; and dibutyl phthalate absorption value of more than 50 cm 3 per 100 g.
Claim 7
Dependent Claim
9 words
A composition of claim 1 also containing a plasticizer.
Claim 8
Dependent Claim
25 words
A composition of claim 6 wherein the plasticizer is a low-melting copolyetherester of a chemical structure similar to the copolyetheresters of formulas (1) and (2).
Claim 9
Dependent Claim
13 words
A dispersion of a conductive composition of claim 1 in an organic solvent.
Claim 10
Dependent Claim
13 words
A conductive film or sheet cast from a wet dispersion of claim 8.
Claim 11
Dependent Claim
10 words
An article fabricated from a conductive composition of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
Maintenance schedule is calculated for granted US utility patents.