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EP0013084A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

A reprocessable thermoplastic graft copolymer of propylene polymer and ethylene copolymer, a process for producing the copolymer, electrical wire or cable when insulated by the copolymer, and reprocessable molded articles when formed from the copolymer

Assignee: Union Carbide Corp
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Filing: 1979-11-30
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Granted: —
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Expires: 1999-11-30
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Abstract

Abstract Graft copolymers are prepared by heating the propylene polymer and ethylene copolymer in the presence of select peroxides in order to graft the propylene polymer onto the ethylene copolymer. These graft copolymers can be used as electrical wire or cable insulation compositions or for forming reprocessable molded articles.

Inventors

  • 👤 Amar Amembal
  • 👤 Robert Bostwick
  • 👤 Richard Gregg Shaw

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 04:57
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08F; C08F255/00; C08F255/02; C08F255/026; C08K; C08K5/00; C08K5/04; C08K5/14; C08L23/0846; C08L23/0853; C08L23/0869; C08L51/00; C08L51/06; C08L23/10; C08L23/12; C08L2312/00; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 63 words
A graft copolymer comprising (A) an ethylene copolymer and (B) a propylene polymer characterized in that the propylene polymer is grafted to the ethylene copolymer with from about 0.1 to about 0.75 weight percent, based on the weight of (A) and (B) of a peroxide having a half life of one minute at > l40 Q C, thereby rendering the graft copolymer reprocessable..
Claim 2
Dependent Claim 63 words
A graft copolymer comprising (A) an ethylene copolymer and (B) a propylene polymer characterized in that the propylene polymer is grafted to the ethylene copolymer with from about 0.1 to about 0.75 weight percent, based on the weight of (A) and (B) of a peroxide having a half life of one minute at > l40 Q C, thereby rendering the graft copolymer reprocessable..
Claim 3
Dependent Claim 23 words
A graft copolymer as claimed in claim 1 wherein the ethylene copolymer contains from about 60 to about 98 weight percent of ethylene.
Claim 4
Dependent Claim 23 words
A graft copolymer as claimed in claim 2 wherein the ethylene copolymer contains from about 80 to about 90 weight percent of ethylene.
Claim 5
Dependent Claim 23 words
A graft copolymer as claimed in any one of claims 1 to 3 wherein the ethylene copolymer is an ethylene/vinyl acetate copolymer .
Claim 6
Dependent Claim 22 words
A graft copolymer as claimed in any one of claims 1 to 3 wherein the ethylene copolymer is an ethylene/ethyl acrylate copolymer.
Claim 7
Dependent Claim 37 words
A graft copolymer as claimed in any one of the preceding claims wherein the peroxide is present in an amount of from about 0.20 to about 0.50 weight percent, based on the weight of (A) and (B).
Claim 8
Dependent Claim 16 words
A graft copolymer as claimed in any one of the preceding claims additionally containing an antioxidant.
Claim 9
Dependent Claim 17 words
A graft copolymer as claimed in any one of the preceding claims additionally containing a carbon black.
Claim 10
Dependent Claim 40 words
A graft copolymer as claimed in any one of the preceding claims containing from about 85 to about 50 percent by weight of the ethylene copolymer and from about 15 to about 50 percent by weight of the propylene polymer.
Claim 11
Dependent Claim 93 words
A process for producing a reprocessable graft copolymer which comprises forming a mixture comprising (A) from about 85 to 50 percent by weight of an ethylene copolymer; (B) from about 15 to 50 percent by weight of a propylene polymer; and (C) from about 0.1 to about 0.75 weight percent, based on the weight of (A) and (B), of a peroxide having a half life of one minute at > 140°C, and heating the mixture at a temperature between about 165 0 and 220°C to graft the propylene polymer to the ethylene copolymer.
Claim 12
Dependent Claim 93 words
A process for producing a reprocessable graft copolymer which comprises forming a mixture comprising (A) from about 85 to 50 percent by weight of an ethylene copolymer; (B) from about 15 to 50 percent by weight of a propylene polymer; and (C) from about 0.1 to about 0.75 weight percent, based on the weight of (A) and (B), of a peroxide having a half life of one minute at > 140°C, and heating the mixture at a temperature between about 165 0 and 220°C to graft the propylene polymer to the ethylene copolymer.
Claim 13
Dependent Claim 24 words
An electrical wire or cable when insulated with a composition comprising a graft copolymer as claimed in any one of claims 1 to 9.
Claim 14
Dependent Claim 22 words
A reprocessable molded article when formed from or comprising a graft copolymer as claimed in any one of claims 1 to 9.

References Cited (Backward Citations)

FR1307186A Cited
FR2271640A1 Cited

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