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CA1236623A Expired / Lapsed CA ⏱️ 0.0 years remaining

Ultraviolet-curable coatings for optical glass fibers having improved adhesion

Assignee: DSM IP Assets BV
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Filing: 1984-10-25
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Granted: 1988-05-10
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Expires: 2004-10-25
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Abstract

Abstract ULTRAVIOLET-CURABLE COATINGS FOR OPTICAL GLASS FIBERS HAVING IMPROVED ADHESION ABSTRACT A liquid radiation-curable coating composition is disclosed which is adapted to deposit, after radiation curing, an adherent cured coating on a glass surface. The coating composition comprises a radiation-curable polyethylenic polymeric organic compound, and from about 0.5% to about 5% of the coating composition of a polyalkoxy silane containing an organic substituent which carries a single active hydrogen atom which is capable of reacting with ethylenic unsaturation by Michael adduction and which is selected from the amino hydrogen atom and the mercaptyl hydrogen atom. Polymethoxy silanes are particularly contemplated, and the coating of glass optical-fibers is especially intended. The compositions of this invention provide improved adhesion to glass, and retention of adhesion upon exposure to high humidity atmospheres is also improved.

Inventors

  • 👤 Timothy E. Bishop

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-10-28 16:28
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/104; C03C25/106; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/61; C08G18/67; C08G18/671; C08G18/672; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; C08G18/83; C08G18/837

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 77 words
A liquid radiation-curable coating composition adapted to deposit, after radiation curing, an adherent cured coating on a glass surface, comprising a radiation-curable polyethylenic polymeric organic compound, and from about 0.5% to about 5% of the coating composition of a polyalkoxy silane containing an organic substituent which carries a single active hydrogen atom which is capable of reacting with ethylenic unsaturation by Michael adduction and which is selected from the amino hydrogen atom and the mercaptyl hydrogen atom.
Claim 2
Dependent Claim 77 words
A liquid radiation-curable coating composition adapted to deposit, after radiation curing, an adherent cured coating on a glass surface, comprising a radiation-curable polyethylenic polymeric organic compound, and from about 0.5% to about 5% of the coating composition of a polyalkoxy silane containing an organic substituent which carries a single active hydrogen atom which is capable of reacting with ethylenic unsaturation by Michael adduction and which is selected from the amino hydrogen atom and the mercaptyl hydrogen atom.
Claim 3
Dependent Claim 19 words
A coating composition as recited in claim 1 in which said active hydrogen atom is an amino hydrogen atom.
Claim 4
Dependent Claim 19 words
A coating composition as recited in claim 1 in which said active hydrogen atom is a mercaptyl hydrogen atom.
Claim 5
Dependent Claim 18 words
A coating composition as recited in claim 1 in which said radiation-curable polyethylenic polymeric organic compound is acrylate-functional.
Claim 6
Dependent Claim 19 words
A coating composition as recited in claim 4 in which said radiation-curable acrylate-functional polymeric organic compound is a polyurethane.
Claim 7
Dependent Claim 20 words
A coating composition as recited in claim 4 in which said radiation-curable acrylate-functional polymeric organic compound is a polyurethane urea.
Claim 8
Dependent Claim 26 words
A coating composition as recited in claim 1 in which said composition cures to provide a film having a tensile modulus less than about 150,000 psi.
Claim 9
Dependent Claim 26 words
A coating composition as recited in claim 1 in which said composition cures to provide a film having a tensile modulus less than about 10,000 psi.
Claim 10
Dependent Claim 31 words
A coating composition as recited in claim 1 in which said radiation-curable polyethylenic polymeric organic compound is acrylate-functional, and a photoinitiator is present to render said composition curable with ultraviolet radiation.
Claim 11
Dependent Claim 15 words
An optical glass fiber coated with a radiation-cured coating of the composition of claim 1.
Claim 12
Dependent Claim 15 words
An optical glass fiber coated with an ultraviolet-cured coating of the composition of claim 9.
Claim 13
Dependent Claim 19 words
A coated optical glass fiber as recited in claim 11 in which said polyalkoxy silane is gamma-mercaptopropyl trimethoxy silane.

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