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CA1189057A Expired / Lapsed CA ⏱️ 0.0 years remaining

Catalyst mixture and process for making 1,2- dichloroethane

Assignee: Hoechst AG
•
Filing: 1982-11-17
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Granted: 1985-06-18
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Expires: 2002-11-17
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Abstract

Abstract ABSTRACT OF THE DISCLOSURE The disclosure relates to a catalyst mixture consisting of anhydrous iron(III)chloride and a further mixing component, for making 1,2-dichloroethane by subjecting ethylene to reac-tion with chlorine in a solvent at atomospheric or elevated pressure. The mixture is more particularly characterized in that the further mixing component is a nitrogen base or a salt thereof, which is used in a proportion approximately equivalent to the iron(III)chloride proportion.

Inventors

  • 👤 Joachim Hundeck
  • 👤 Harald Scholz
  • 👤 Hans Hennen

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-09 05:14
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/06; B01J27/08; B01J27/10; C; C07; C07C; C07C17/00; C07C17/013; C07C17/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 51 words
A process for making 1,2-dichloroethane by subjecting ethylene to reaction with chlorine in a solvent at atmospheric or elevated pressure in the presence of a catalyst mixture con-sisting of anhydrous iron(III)chloride and a nitrogen base or a salt thereof, which is used in a proportion approximately equi-valent to the iron(III)chloride proportion.
Claim 2
Dependent Claim 51 words
A process for making 1,2-dichloroethane by subjecting ethylene to reaction with chlorine in a solvent at atmospheric or elevated pressure in the presence of a catalyst mixture con-sisting of anhydrous iron(III)chloride and a nitrogen base or a salt thereof, which is used in a proportion approximately equi-valent to the iron(III)chloride proportion.
Claim 3
Dependent Claim 85 words
A process for making 1,2-dichloroethane by subjecting ethylene to reaction with chlorine in a solvent at atmospheric or elevated pressure in the presence of a catalyst mixture con-sisting of anhydrous iron(III)chloride in a concentration of 0.005 to about 0.5 weight %, based on the quantity of solvent and a nitrogen base or a salt thereof, which is used in a pro-portion approximately equivalent to the iron(III)chloride pro-portion, and, if desired, an agent inhibiting the formation of by-products at a temperature of about 20 to 200°C.
Claim 4
Dependent Claim 85 words
A process for making 1,2-dichloroethane by subjecting ethylene to reaction with chlorine in a solvent at atmospheric or elevated pressure in the presence of a catalyst mixture con-sisting of anhydrous iron(III)chloride in a concentration of 0.005 to about 0.5 weight %, based on the quantity of solvent and a nitrogen base or a salt thereof, which is used in a pro-portion approximately equivalent to the iron(III)chloride pro-portion, and, if desired, an agent inhibiting the formation of by-products at a temperature of about 20 to 200°C.
Claim 5
Dependent Claim 28 words
The process as claimed in claim 1 or 2, wherein the nitrogen base is NH3, a primary, secondary or tertiary alkyl, aralkyl, aryl or alicyclic amine or polyamine.
Claim 6
Dependent Claim 20 words
The process as claimed in claim 1 or 2, wherein the salt of the nitrogen base is a halogen salt.
Claim 7
Dependent Claim 19 words
The process as claimed in claim 1 or 2, wherein the salt of the nitrogen base is ammonium chloride.
Claim 8
Dependent Claim 14 words
The process as claimed in claim 1 or 2, wherein the solvent is 1,2-dichloroethane.
Claim 9
Dependent Claim 13 words
The process as claimed in claim 2, wherein the inhibit-ing agent is oxygen.

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