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CA1186458A Expired / Lapsed CA ⏱️ 0.0 years remaining

Method for simultaneously washing and softening fabrics in an automatic washer and compositions therefor

Assignee: Bristol Myers Squibb Co
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Filing: 1982-04-22
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Granted: 1985-05-07
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Expires: 2002-04-22
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Abstract

Abstract Abstract: Methods of simultaneously washing, softening, and controlling static electricity in an automatic washer are disclosed. In accordance with these methods a composition of this invention is added to an automatic washer along with a conventional detergent and the fabrics to be laundered, each of which is added at the initiation of the wash cycle. The compositions disclosed contain a primary secondary or tertiary amine or a salt thereof. These compositions are either in a granular form, which contains an adjuvant and a particulate amine having a particle size of less than 420 microns, or in a liquid form, which is aqueous based with a pH of less than 7 and contains an acid and a salt of one of the amine compounds.

Inventors

  • 👤 Joseph A. Bolan
  • 👤 Thomas J. Carrothers
  • 👤 Earl B. Krentz

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-01 03:31
CPC Classifications
—

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 211 words
The process of softening fabrics in an automatic washer during the wash cycle of the automatic washer which comprises the steps of: (a) adding a premeasured amount of a conven-tional laundry detergent and fabrics to be laundered to the washer; (b) activating the washer so that the tub of the washer fills with water; (c) adding an effective amount of: (i) a granular material containing a mixture of an adjuvant and a particulate nitrogen containing compound having a particle size of less than 420 microns and said nitrogen containing compound being selected from the group consisting of primary amines, secondary amines, tertiary amines, and the acetate, sulfate or hydrochloride salts thereof, wherein said amines and their salts have at least one straight chain organic radical of between 8 and 22 carbon atoms and wherein the ratio of adjuvant to nitrogen containing compound is from about 15:1 to about 2:1; or (ii) an aqueous based composition having a pH of less than 7 and containing a nitrogen containing compound selected from the group consisting of the acetate, sulfate, and hydrochloride salts of primary, secondary, or tertiary, amines having at least one straight chain organic radical of between 8 and 22 carbon atoms; and (d) operating the washer through all of its cycles.
Claim 2
Dependent Claim 211 words
The process of softening fabrics in an automatic washer during the wash cycle of the automatic washer which comprises the steps of: (a) adding a premeasured amount of a conven-tional laundry detergent and fabrics to be laundered to the washer; (b) activating the washer so that the tub of the washer fills with water; (c) adding an effective amount of: (i) a granular material containing a mixture of an adjuvant and a particulate nitrogen containing compound having a particle size of less than 420 microns and said nitrogen containing compound being selected from the group consisting of primary amines, secondary amines, tertiary amines, and the acetate, sulfate or hydrochloride salts thereof, wherein said amines and their salts have at least one straight chain organic radical of between 8 and 22 carbon atoms and wherein the ratio of adjuvant to nitrogen containing compound is from about 15:1 to about 2:1; or (ii) an aqueous based composition having a pH of less than 7 and containing a nitrogen containing compound selected from the group consisting of the acetate, sulfate, and hydrochloride salts of primary, secondary, or tertiary, amines having at least one straight chain organic radical of between 8 and 22 carbon atoms; and (d) operating the washer through all of its cycles.
Claim 3
Dependent Claim 28 words
The process of Claim 1 wherein the particle size of said particulate nitrogen containing compound has a particle size of from about 15 microns to about 420 microns.
Claim 4
Dependent Claim 28 words
The process of Claim 2 wherein the particle size of said particulate nitrogen containing compound has a particle size of from about 50 microns to about 150 microns.
Claim 5
Dependent Claim 31 words
The process of Claim 1 wherein the adjuvant is selected from the group consisting of sodium sesqui-carbonate, sodium borate decahydrate, sodium carbonate, sodium sulfate, sodium tripolyphosphate, sodium silicate, and trisodium nitrilotriacetate.
Claim 6
Dependent Claim 23 words
The process of Claim 3 wherein the straight chain organic radical of the nitrogen containing compound has between 12 and 22 carbon atoms.
Claim 7
Dependent Claim 23 words
The process of Claim 4 wherein the straight chain organic radical of the nitrogen containing compound has between 12 and 22 carbon atoms.
Claim 8
Dependent Claim 21 words
The process of Claim 5 or 6 wherein the nitrogen containing compound is octadecylamine, hydrogenated-tallow amine, or the acetate salts thereof.
Claim 9
Dependent Claim 116 words
A fabric conditioning composition adapted to condition fabrics in an automatic washer comprised of: (a) an adjuvant selected from the group consisting of sodium sesquicarbonater sodium borate decahydrate, sodium carbonate, sodium sulfate, sodium tripolyphosphate, sodium silicate, trisodium nitrilotriacetate; (b) an effective amount of a particulate nitrogen containing compound selected from the group consisting of primary amines, secondary amines, tertiary amines, mixtures thereof, and their acetate, hydrochloride and sulfate salts, wherein said nitrogen containing compounds have at least one straight chain organic radical of between 8 and 22 carbon atoms, and having a particle size of less than 420 microns; wherein the weight ratio of adjuvant to nitrogen containing compound is from about 15:1 to about 2:1.
Claim 10
Dependent Claim 116 words
A fabric conditioning composition adapted to condition fabrics in an automatic washer comprised of: (a) an adjuvant selected from the group consisting of sodium sesquicarbonater sodium borate decahydrate, sodium carbonate, sodium sulfate, sodium tripolyphosphate, sodium silicate, trisodium nitrilotriacetate; (b) an effective amount of a particulate nitrogen containing compound selected from the group consisting of primary amines, secondary amines, tertiary amines, mixtures thereof, and their acetate, hydrochloride and sulfate salts, wherein said nitrogen containing compounds have at least one straight chain organic radical of between 8 and 22 carbon atoms, and having a particle size of less than 420 microns; wherein the weight ratio of adjuvant to nitrogen containing compound is from about 15:1 to about 2:1.
Claim 11
Dependent Claim 23 words
The composition of Claim 8 wherein the straight chain organic radical of the nitrogen containing compound has between 12 and 22 carbon atoms.
Claim 12
Dependent Claim 23 words
The composition of Claim 9 wherein the nitrogen containing compound has a particle size of from about 50 microns to about 150 microns.
Claim 13
Dependent Claim 22 words
The composition of Claim 10 wherein the weight ratio of adjuvant to nitrogen containing compound is from about 10:1 to about 5:1.
Claim 14
Dependent Claim 18 words
The composition of Claim 11 wherein the nitrogen containing compound is octadecylamine, hydro-genated-tallow amine or the acetates thereof.
Claim 15
Dependent Claim 17 words
The composition of Claim 12 wherein the weight of adjuvant to nitrogen containing compound is about 8:1.
Claim 16
Dependent Claim 23 words
The composition of Claim 13 wherein the effective amount of the nitrogen containing compound is from about 4 grams to about 25 grams.
Claim 17
Dependent Claim 154 words
A laundry detergent composition comprising: (a) from 0.5 to about 20% by weight of a detergent compound selected from the group consisting of anionic surfactants and mixtures of anionic and nonionic surfactants, and (b) from 99.5 to about 80% of a fabric conditioning composi-tion adapted to condition fabrics in the wash cycle of an automatic washer consisting essentially of: (i) an adjuvant selected from the group of sodium sesquicarbonate, sodium borate decahydrate, sodium carbonate, sodium sulfate, sodium tripolyphosphate, sodium silicate, trisodium nitrilotriacetate, and (ii) a particulate nitrogen-containing com-pound selected from the group consisting of primary amines, secondary amines, ter-tiary amines, and mixtures thereof, and their acetate, hydrochloride and sulfate salts, wherein said nitrogen-containing compounds have at least one straight chain organic radical of between 8 to 22 carbon atoms, and have a particle size of less than 420 microns, the weight ratio of adjuvant to nitrogen-containing compound being from about 15:1 to about 2:1.
Claim 18
Dependent Claim 154 words
A laundry detergent composition comprising: (a) from 0.5 to about 20% by weight of a detergent compound selected from the group consisting of anionic surfactants and mixtures of anionic and nonionic surfactants, and (b) from 99.5 to about 80% of a fabric conditioning composi-tion adapted to condition fabrics in the wash cycle of an automatic washer consisting essentially of: (i) an adjuvant selected from the group of sodium sesquicarbonate, sodium borate decahydrate, sodium carbonate, sodium sulfate, sodium tripolyphosphate, sodium silicate, trisodium nitrilotriacetate, and (ii) a particulate nitrogen-containing com-pound selected from the group consisting of primary amines, secondary amines, ter-tiary amines, and mixtures thereof, and their acetate, hydrochloride and sulfate salts, wherein said nitrogen-containing compounds have at least one straight chain organic radical of between 8 to 22 carbon atoms, and have a particle size of less than 420 microns, the weight ratio of adjuvant to nitrogen-containing compound being from about 15:1 to about 2:1.
Claim 19
Dependent Claim 23 words
The composition of Claim 15 further comprising at least one of the following materials: enzymes, dyes, fragrances, bacterio-stats, optical brighteners, and bleaching agents.
Claim 20
Dependent Claim 46 words
The composition of Claim 15 wherein the anionic surfactant is selected from the group consisting of alpha olefin sulfonates, linear alkyl benzene sulfonate, and sodium lauryl sulfate, and wherein the nonionic surfactant is selected from the group con-sisting of nonyl phenol ethoxylates and primary ethoxylated alcohols.
Claim 21
Dependent Claim 23 words
The composition of Claim 15 wherein the straight chain organic radical of the nitrogen containing compound has between 12 and 22 carbon atoms.

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