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CA1153356A Expired / Lapsed CA ⏱️ 0.0 years remaining

High viscosity fluids

Assignee: Texaco Development Corp
•
Filing: 1981-08-14
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Granted: 1983-09-06
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Expires: 2001-08-14
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Abstract

Abstract HIGH VISCOSITY FLUIDS (D#75,830-F) ABSTRACT OF THE DISCLOSURE High viscosity fluids and their method of manu-facture by reacting epoxy resin with ethylene oxide/propylene oxide adducts of alcohols, glycols and other polyhydric initiators are described. Fluids made by the method of this invention have viscosities on the order of 300,000 to 400,000 SUS at 100°F as compared with prior art synthetic fluids which have viscosities around 200,000 SUS at 100°F. The fluids described have good water solubility and thickening properties and may be used as functional fluids. The fluids of this invention may be made by a more economical method than those of the prior art. -I-

Inventors

  • 👤 Michael Cuscurida
  • 👤 George P. Speranza

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-01 20:23
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2603; C08G65/2606; C08G65/2609; C08L; C08L63/00

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 150 words
Water soluble high viscosity fluids made by the process comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction with the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl equivalents to epoxy equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consisting of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogenated diglycidyl ether of Bis-phenol A, 1,4-butanediol diglycidyl ether, diglycidyl ether of propylene glycol, vinylcyclohexanediepoxide, halogenated diglycidyl ethers of Bis-phenol A and aromatic amine based epoxy resins to produce fluids having a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 2
Dependent Claim 150 words
Water soluble high viscosity fluids made by the process comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction with the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl equivalents to epoxy equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consisting of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogenated diglycidyl ether of Bis-phenol A, 1,4-butanediol diglycidyl ether, diglycidyl ether of propylene glycol, vinylcyclohexanediepoxide, halogenated diglycidyl ethers of Bis-phenol A and aromatic amine based epoxy resins to produce fluids having a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 3
Dependent Claim 26 words
The high viscosity fluids of claim 1 in which the alkylene oxides are taken from the group consisting of ethylene oxide, propylene oxide and 1,2-butylene oxide.
Claim 4
Dependent Claim 30 words
The high viscosity fluids of claim 1 in which the components are heated in the range of about 50 to 120°C during the process of making the high viscosity fluids.
Claim 5
Dependent Claim 145 words
Water soluble high viscosity fluids made by the process comprising a) reacting a diol initiator with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction with the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl equiva-lents to epoxy equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consisting of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formalde-hyde novolac resin, hydrogenated di-glycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinylcyclohexanediepoxide, halogen-ated diglycidyl ethers of Bisphenol A, and aromatic amine based epoxy resins to produce fluids having a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 6
Dependent Claim 145 words
Water soluble high viscosity fluids made by the process comprising a) reacting a diol initiator with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction with the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl equiva-lents to epoxy equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consisting of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formalde-hyde novolac resin, hydrogenated di-glycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinylcyclohexanediepoxide, halogen-ated diglycidyl ethers of Bisphenol A, and aromatic amine based epoxy resins to produce fluids having a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 7
Dependent Claim 153 words
A process for the preparation of water soluble, high viscosity fluids comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins con-sisting of diglycidyl ether of Bis-phenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogen-ated diglycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinyl-cyclohexanediepoxide, halogenated di-glycidyl ethers of Bisphenol A and aro-matic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 8
Dependent Claim 153 words
A process for the preparation of water soluble, high viscosity fluids comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins con-sisting of diglycidyl ether of Bis-phenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogen-ated diglycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinyl-cyclohexanediepoxide, halogenated di-glycidyl ethers of Bisphenol A and aro-matic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 9
Dependent Claim 24 words
The process of claim 5 in which the alkylene oxides are taken from the group consisting of ethylene oxide, propylene oxide and butylene oxide.
Claim 10
Dependent Claim 20 words
The process of claim 5 in which the components are heated during the reaction of making the high viscosity fluids.
Claim 11
Dependent Claim 148 words
A process for the preparation of water sol-uble, high viscosity fluids comprising a) reacting a diol initiator with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consist-ing of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formalde-hyde novolac resin, hydrogenated digly-cidyl ether of Bisphenol A, 1,4-butane-diol diglycidyl ether, diglycidyl ether of propylene glycol, vinylcyclohexanedi-epoxide, halogenated diglycidyl ethers of Bisphenol A and aromatic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 12
Dependent Claim 148 words
A process for the preparation of water sol-uble, high viscosity fluids comprising a) reacting a diol initiator with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins consist-ing of diglycidyl ether of Bisphenol A, polyglycidyl ether of phenol formalde-hyde novolac resin, hydrogenated digly-cidyl ether of Bisphenol A, 1,4-butane-diol diglycidyl ether, diglycidyl ether of propylene glycol, vinylcyclohexanedi-epoxide, halogenated diglycidyl ethers of Bisphenol A and aromatic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 13
Dependent Claim 161 words
Aqueous solutions of high viscosity fluids comprising water and a water soluble, high viscosity fluid made by the process comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins con-sisting of diglycidyl ether of Bis-phenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogen-ated diglycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinyl-cyclohexanediepoxide, halogenated di-glycidyl ethers of Bisphenol A and aro-matic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.
Claim 14
Dependent Claim 161 words
Aqueous solutions of high viscosity fluids comprising water and a water soluble, high viscosity fluid made by the process comprising a) reacting one or more monohydric or di-hydric alcohol initiators with one or more alkylene oxides to give an adduct having a molecular weight in the range of about 2,000 to 20,000, and b) terminating the reaction by the ad-dition of a quantity of epoxy resin such that the ratio of hydroxyl to epoxy resin equivalents is in the range of about 2 to 1 to about 5 to 1, where the epoxy resin is selected from the group of epoxy resins con-sisting of diglycidyl ether of Bis-phenol A, polyglycidyl ether of phenol formaldehyde novolac resin, hydrogen-ated diglycidyl ether of Bisphenol A, 1,4-butanediol diglycidyl ether, digly-cidyl ether of propylene glycol, vinyl-cyclohexanediepoxide, halogenated di-glycidyl ethers of Bisphenol A and aro-matic amine based epoxy resins where the resulting fluids have a viscosity in the range of about 200,000 to 400,000 SUS at 100°F.

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