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CA1056769A Expired / Lapsed CA ⏱️ 0.0 years remaining

Cathode for electrolytic systems

Assignee: Gow Enterprises Ltd
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Filing: 1975-07-28
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Granted: 1979-06-19
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Expires: 1995-07-28
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Abstract

Abstract ABSTRACT OF THE DISCLOSURE Novel electrolytic cells and electrodes, e.g. cathodes and bipolar cathodes/anodes therefor are provided. The electrode comprises titanium base metal in self-sustaining form, e.g., in flat sheet form the surfaces of which having a high surface area, any pores or apertures in the central core being smaller than pores or apertures at the surface, so that the central core is less porous or more dense, the sheet being in accordion-type form, of mesh-like form, of grid-like form, or of expanded metal form. The exposed cathodically active surfaces are of high surface area, i.e., being microporous and more porous than the surface of the sheet in which it is provided. They may e.g. be provided by grit blasting the base titanium, or by subjecting the base titanium to electrolysis, or by sintering or by fus-ing powered titanium. The cathode has the advantages of a steel or carbon cathode and yet does not suffer the disadvantages thereof. The electrolytic cell comprises a plurality of anodes and cathodes, preferably m the form of end-to-end bipolar electrodes the cathodes each being as described above, namely, comprising titanium base metal in self-sustaining form, whose exposed cathodically active surfaces are of high surface area.

Inventors

  • 👤 H. Benny Westerlund

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-05 13:43
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/02; C25B11/03; C25B11/04; C25B11/042

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 94 words
A cathode for an electrolytic cell comprising (a) a titanium sheet having a central core and surfaces having high surface areas, any pores or apertures in the central core being of lesser diameter than the pores at the surfaces, thereby providing a central core of less porosity than the surfaces; and (b) the exposed surfaces of at least two side faces thereof being microporous titanium, the titanium having pores of greater diameter than those of the core and thus being more porous than the surface of the titanium sheet on which it is provided.
Claim 2
Dependent Claim 94 words
A cathode for an electrolytic cell comprising (a) a titanium sheet having a central core and surfaces having high surface areas, any pores or apertures in the central core being of lesser diameter than the pores at the surfaces, thereby providing a central core of less porosity than the surfaces; and (b) the exposed surfaces of at least two side faces thereof being microporous titanium, the titanium having pores of greater diameter than those of the core and thus being more porous than the surface of the titanium sheet on which it is provided.
Claim 3
Dependent Claim 14 words
A cathode according to claim 1, wherein the core is sintered micro sized powder.
Claim 4
Dependent Claim 45 words
A cathode as claimed in claim 1 comprising a sintered micro-porous titanium sheet having a central core and two side faces, the central core formed from smaller size titanium powder than the two side faces, and having a lower porosity than the two side faces.
Claim 5
Dependent Claim 25 words
A cathode according to claim 3, wherein the central core has a porosity of 20% and the two side faces have a porosity of 75%.
Claim 6
Dependent Claim 12 words
The cathode of claim 1 wherein the pore size is 3-30 microns.
Claim 7
Dependent Claim 15 words
The cathode of claims 1 or 5 wherein the porosity of the sur-face is 70%.
Claim 8
Dependent Claim 16 words
The cathode of claims 1 or 2 wherein said titanium sheet is in flat sheet form.
Claim 9
Dependent Claim 15 words
The cathode of claims 1 or 2 wherein said titanium sheet is in accordian-type form.
Claim 10
Dependent Claim 17 words
The cathode of claims 1 or 2 or 3 wherein said titanium sheet is of mesh-like form.
Claim 11
Dependent Claim 15 words
The cathode of claims 1 or 2 wherein said titanium sheet is of grid-like form.
Claim 12
Dependent Claim 16 words
The cathode of claims 1 or 2 wherein said titanium sheet is of expanded metal form.
Claim 13
Dependent Claim 21 words
The cathode of claims 1, 2 or 3 wherein the high surface area is provided by grit blasting said titanium sheet.
Claim 14
Dependent Claim 33 words
The cathode of claims 1, 2 or 3 wherein said surfaces having high surface-areas are provided by grit blasting the base titanium and wherein the grit used in grit blasting is aluminum oxide.
Claim 15
Dependent Claim 25 words
The cathode of claims 1, 2 or 3 wherein said surfaces having high surface areas are provided by subjecting the base titanium to electro-lytic dissolving.
Claim 16
Dependent Claim 43 words
The cathode of claims 1, 2 or 3 wherein said surfaces having high surface areas are provided by subjecting the base titanium to electro-lytic dissolving and wherein the electrochemical dissolving is effective in a chloride electrolytic at a voltage slightly above decomposition voltage.
Claim 17
Dependent Claim 22 words
The cathode of claims 1, 2 or 3 wherein the cathode has a microporous surface provided by sintering or fusing powdered titanium.
Claim 18
Dependent Claim 13 words
The cathode of claims 1, 2 or 3 which has additionally been anodized.
Claim 19
Dependent Claim 21 words
The cathode of claims 1, 2 or 3 which has additionally been anodized in chloride water solution or in caustic solution.
Claim 20
Dependent Claim 32 words
An electrolytic cell comprising a plurality of alternating anodes and cathodes, each of said cathodes comprising the cathode as claimed in claims 1, 2 or 3. CLAIMS SUPPORTED BY THE SUPPLEMENTARY DISCLOSURE
Claim 21
Dependent Claim 59 words
An electrode as claimed in claim 1 comprising an expanded titanium cathode core, having a coating acting as a cathode along a portion of its length, on both sides thereof, said coating comprising a pressed and sintered powdered titanium porous coating, and a surface acting as an anode on both sides thereof along the remaining portion of its length.
Claim 22
Dependent Claim 31 words
The electrode as claimed in claim 17 wherein the portion of the titanium sheet acting as an anode is provided with a coating on the sur-face thereof acting as an anode.
Claim 23
Dependent Claim 18 words
The electrode as claimed in claim 18 wherein the coating acting as an anode is formed of platinum.
Claim 24
Dependent Claim 29 words
The electrode as claimed in claim 17 wherein the end face of the portion of the electrode acting as a cathode is provided with an electrically non-conductive electrode spacer.

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