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AU1237688A Expired / Lapsed AU ⏱️ 0.0 years remaining

Substituted phthalocyanine

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1988-02-29
•
Granted: —
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Expires: 2008-02-29
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Abstract

Abstract A phthalocyanine compound of the formula: (R-X-)m Pc (-Y-R<1>-Z-)n (-SO3M)p I wherein Pc is a phthalocyanine nucleus (Pc); each R independently is a monovalent aromatic radical linked to a peripheral carbon atom of the Pc nucleus through X; X selected from S, Se and Te; m is 4 to 16; each R<1> independently is a divalent aromatic radical linked to two adjacent peripheral carbon atoms of the Pc nucleus through Y and Z; Y is selected from S, NT, Se and Te; Z is selected from S, Se, Te, NT and 0; T is selected from H, alkyl and aryl; n is 0 to 7; M is H, a metal or optionally-substituted ammonium; and p is from 1 to 16. The compounds have a significant absorption band in the near infra red and depending on the number of sulphonic acids groups and the nature of the counter ion are soluble in aqueous and polar organic media. The compounds are useful in many applications where absorption of infra-red radiation is desirable, such as in OCR readable inks, rapid-drying inks, security printing and reprographic toners.

Inventors

  • 👤 Donald Murray Gunn
  • 👤 Nigel Hughes
  • 👤 William Marshall Stark

Bibliographic Details

Application Number —
Jurisdiction AU
Data Source google_patents
Last Synchronized 2026-11-04 01:18
CPC Classifications
C; C07; C07D; C07D487/00; C07D487/22; C09; C09D; C09D11/00; C09D11/02; C09D11/03; C09D11/037; C09B; C09B47/00; C09B47/04; C09B47/045; C09B47/08; C09B47/20; C09B47/24; G; G03; G03G; G03G9/00; G03G9/08; G03G9/09; G03G9/0906; G03G9/0918

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 119 words
A phthalocyanine compound of the formula: Pc n (-SOM) I wherein Pc is a phthalocyanine nucleus (Pc); each R independently is a monovalent aromatic radical linked to a peripheral carbon atom of the Pc nucleus through X; X selected from S, Se and Te; m is 4 to 16; each RI independently is a divalent aromatic radical linked to two adjacent peripheral carbon atoms of the Pc nucleus through Y and Z; Y is selected from S, NT, Se and Te; Z is selected from S, Se, Te, NT and 0; T is selected from H, alkyl and aryl; n is 0 to 7; M is H, a metal or optionally-substituted ammonium; and p is from 1 to 16.
Claim 2
Dependent Claim 119 words
A phthalocyanine compound of the formula: Pc n (-SOM) I wherein Pc is a phthalocyanine nucleus (Pc); each R independently is a monovalent aromatic radical linked to a peripheral carbon atom of the Pc nucleus through X; X selected from S, Se and Te; m is 4 to 16; each RI independently is a divalent aromatic radical linked to two adjacent peripheral carbon atoms of the Pc nucleus through Y and Z; Y is selected from S, NT, Se and Te; Z is selected from S, Se, Te, NT and 0; T is selected from H, alkyl and aryl; n is 0 to 7; M is H, a metal or optionally-substituted ammonium; and p is from 1 to 16.
Claim 3
Dependent Claim 11 words
A compound according to Claim 1 in which Pc is Cu(II)Pc.
Claim 4
Dependent Claim 66 words
A compound according to Claim 1 wherein R is selected from phenyl, naphthyl, thienyl, furyl, pyrryl, thiazolyl, isothiazolyl, quinolyl, indolyl, pyridyl, benzoimidazolyl and benzothiazolyl, each of which is unsubstituted or is substituted by up to 3 substituents selected from C alkyl, 0-C 20-alkoxy, S-C 20-alkyl, aryl S-aryl, halogen, nitro, cyano, dialkyl-, N-alkyl-N-aryl- and diaryl- amino, -COOH, acyl and acylamino, SO2 T1 and SO NT T2. 1
Claim 5
Dependent Claim 73 words
A compound according to Claim 1 wherein R is selected from phenylene or naphthylene each of which is unsubstituted or is substituted by up to 3 substituents selected from C1- 2 0 -alkyl, 0-C 1 2 0 -alkoxy, S-C 1 20 -alkyl, aryl S-aryl, halogen, nitro, cyano, dialkyl-, N-alkyl-N-aryl- and diaryl- amino, -COOH, acyl and acylamino, SO2 T and SO 2NT T Dn 34238 A compound according to Claim 1 wherein Y is
Claim 6
Dependent Claim 4 words
S, Se or Te.
Claim 7
Dependent Claim 4 words
S, Se or Te.
Claim 8
Dependent Claim 51 words
A com'pound according to Claim 1 or Claim 5 wherein the substituted amnmonium group is of the formula, NQ V in which at least one Q is a fatty aliphatic group or two Qg, together with the N atom, form an heteroalicyclic. or heteroaromatic group selected from pyridino, piperidino and morpholino.
Claim 9
Dependent Claim 19 words
A compound according to Ml=r 6 wherein the fatty aliphatic group represented by Q is C6 2 0 -alkyl.
Claim 10
Dependent Claim 19 words
A compound according to Ml=r 6 wherein the fatty aliphatic group represented by Q is C6 2 0 -alkyl.
Claim 11
Dependent Claim 45 words
A compound according to Claim 7 wherein Q is Wan~.ted from 3,5,5-triethylhexyl., 2-ethyihexyl, 1,1,3,3-tetrarnethylbutyl, 1,2,2-trimethyipropyl, 2-ethylbutyl, I-propylbutyl, 1,2-dimaethyl- butyl, 2-methylpentyl, I-ethylpentyl, 1,4-dimethylpentyi, 1-ethyl- 3-methylpentyl, hexyl, 1-methylhexyl, 3-methylhexyl, 1,3,3-triniethyl- butyl, 1,5-dimethyl- hexyl, heptyl, 1-maethyiheptyl, 1,4-dimethyl- heptyl, octyl, nonyl, 1-methylnonyl, decyl, dodecyl, tridecyl, pentadecyl, hexadecyl and octadecyl-.
Claim 12
Dependent Claim 109 words
A compound according to Claim 6 wherein one Q is C8 9 alkyl and the other three qs are H. A compound according to Claim I wherein PC Is Cu(II)Pc; R is phenyl, C 4 -alkylphenyl or C1 4 alkoxyphenyl; X La S; m is 8 to 16; R 1is phen-1,2-ylene, naphth-1,2-ylene or naphth-2,3-ylene; Y is S; n is 0 to 4; Z is NT, S or 0 T is H or C1 4 -alIkyl M is selected from H, alkali metal, NR-i 4P N 3Q and diarylguanidinium; and Q is a CB 9 -alkyl. DATED: 26 February, 1988 PHILLIPS ORMONDE AND FITZPATRICK Attorneys for: IMPERIAL CHEMICAL INDUSTRIES PLC

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